ECTS
3 crédits
Composante
UFR Chimie, UFR des Sciences fondamentales et biomédicales
Volume horaire
24h
Période de l'année
Semestre 2
Description
The first part of this course gives a brief presentation of molecular orbital theory (Hückel for conjugated p-systems)
then addresses pericyclic reactions and different methods (Dewar-Zimmermann, Woodward-Hofmann rules and Fukui’s method)
used to rationalize many aspects of these reactions. The second part is dedicated to stereoelectronic effects and their importance
in explaining the molecular shape, conformation, stability, reactivity and selectivity. The last part addresses the reaction mechanism
determination aiming to prepare you to (1) elucidate the mechanism of chemical reactions based on kinetic and thermodynamic
principles and collected data, and (2) be able to evaluate mechanistic arguments made in the literature.
Heures d'enseignement
- Orbitals reactivity and mechanismsCours Magistral12h
- Orbitals reactivity and mechanismsTravaux Dirigés12h
Pré-requis nécessaires
Prior organic courses in years 1-3, in particular year 3 courses of organic chemistry and physical
chemistry
Dernière mise à jour le 21 octobre 2025


