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Stoichiometric organometallics

  • ECTS

    3 crédits

  • Composante

    UFR Chimie, UFR des Sciences fondamentales et biomédicales

  • Volume horaire

    24h

  • Période de l'année

    Semestre 2

Description

This module is intended to provide you with sufficient knowledge regarding the formation,
stability and reactivity of the most frequent and useful stoichiometric organometallics and enolates.
Topics will include (1) organometallics derived from lithium, magnesium, copper, and zinc, and (2)
enolates and aza-enolates chemistry. A particular attention will be paid to the selectivity aspects of their
preparation and reactivity, some predictive models of simple diastereoselectivity will be discussed. We
will examine the applications of these reagents to the construction of complex organic molecules.

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Heures d'enseignement

  • Stoichiometric organometallicsCours Magistral12h
  • Stoichiometric organometallicsTravaux Dirigés12h

Pré-requis nécessaires

Stoichiometric organometallics, synthesis and reactivity, C-C bond formation,
diastereoselectivity, chiral auxiliary

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